Kinetic characterization of spiropyrans in aqueous media.
نویسندگان
چکیده
Detailed kinetic investigations of the most common photoswitchable spiropyran, 6-nitro-BIPS, reveal that hydrolytic decomposition of its merocyanine isomer limits its utility in aqueous buffer; however, simple replacement of the 6-nitro substituent with an 8-carboxylate yields a BIPS photoswitch that is potentially better suited for biological applications.
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ورودعنوان ژورنال:
- Chemical communications
دوره 3 شماره
صفحات -
تاریخ انتشار 2009